The claisen rearrangement is a powerful carbon carbon bond forming chemical reaction discovered by rainer ludwig claisen the heating of an allyl vinyl ether will initiate a 3 3 sigmatropic rearrangement to give a γ δ unsaturated carbonyl. The claisen rearrangement not to be confused with the claisen condensation is a powerful carbon carbon bond forming chemical reaction discovered by rainer ludwig claisen in 1912. Substrate induced diastereoselectivity and reagent induced enantioselectivity with stoichiometric amounts of external chiral auxiliaries have frequently been exploited to control the.
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